Photochemical reactions of palladium(0) and platinum(0) phosphine complexes

Taro Tsubomura, Ken Sakai

研究成果: Contribution to journalArticle査読

20 被引用数 (Scopus)

抄録

Photochemical reactions of the binuclear palladium(0) complex [Pd2(dppm)3] with organic halides yield palladium(I) dihalogeno complexes with irradiation of visible light. Photooxidation of alcohols was observed for ethanol and 2-propanol with the palladium complex, Photophysical and quenching properties of a chiral [Pt(BINAP)2] complex (BINAP = RR-or SS-2,2′-bis(diphenylphosphino)-1,1′-binaphthyl) were studied. The emitting MLCT excited state has a long lifetime. Photochemical reactions of [Pt(BINAP)2] with organic halides cause halogen abstraction. Atom and electron transfer may be candidates for the initial stage of the photoreaction. The mechanism of the photoreaction is discussed with the quenching data.

本文言語英語
ページ(範囲)107-113
ページ数7
ジャーナルCoordination Chemistry Reviews
171
1
DOI
出版ステータス出版済み - 4 1998
外部発表はい

All Science Journal Classification (ASJC) codes

  • Physical and Theoretical Chemistry
  • Inorganic Chemistry
  • Materials Chemistry

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