Photocontrol of micellar catalysis

Seiji Shinkai; Katsuta Matsuo; Michiko Sato; Takaaki Sone; Osamu Manabe

doi:10.1016/S0040-4039(01)90335-1

Photocontrol of micellar catalysis

Seiji Shinkai, Katsuta Matsuo, Michiko Sato, Takaaki Sone, Osamu Manabe

研究成果: Contribution to journal › Article › 査読

11 被引用数 (Scopus)

抄録

A photoresponsive surfactant with a cationic azobenzene head group (I) was synthesized. It was demonstrated that by mixing (I) with a conventional cationic micelle the rate of the micelle-catalyzed reaction (base-catalyzed proton abstraction from benzoin) can be controlled by light. The origin of the photocontrol was accounted for by the difference in the partitioning of trans-(I) and cis-(I) in the micelle phase.

本文言語	英語
ページ（範囲）	1409-1412
ページ数	4
ジャーナル	Tetrahedron Letters
巻	22
号	15
DOI	https://doi.org/10.1016/S0040-4039(01)90335-1
出版ステータス	出版済み - 1981
外部発表	はい

All Science Journal Classification (ASJC) codes

Biochemistry
Drug Discovery
Organic Chemistry

文献へのアクセス

10.1016/S0040-4039(01)90335-1

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引用スタイル

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abstract = "A photoresponsive surfactant with a cationic azobenzene head group (I) was synthesized. It was demonstrated that by mixing (I) with a conventional cationic micelle the rate of the micelle-catalyzed reaction (base-catalyzed proton abstraction from benzoin) can be controlled by light. The origin of the photocontrol was accounted for by the difference in the partitioning of trans-(I) and cis-(I) in the micelle phase.",

author = "Seiji Shinkai and Katsuta Matsuo and Michiko Sato and Takaaki Sone and Osamu Manabe",

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AU - Shinkai, Seiji

AU - Matsuo, Katsuta

AU - Sato, Michiko

AU - Sone, Takaaki

AU - Manabe, Osamu

PY - 1981

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AB - A photoresponsive surfactant with a cationic azobenzene head group (I) was synthesized. It was demonstrated that by mixing (I) with a conventional cationic micelle the rate of the micelle-catalyzed reaction (base-catalyzed proton abstraction from benzoin) can be controlled by light. The origin of the photocontrol was accounted for by the difference in the partitioning of trans-(I) and cis-(I) in the micelle phase.

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