Photodissociation of acrylonitrile cluster anions

Yuji Fukuda, Tatsuya Tsukuda, Akira Terasaki, Tamotsu Kondow

研究成果: Contribution to journalArticle査読

14 被引用数 (Scopus)

抄録

Acrylonitrile (AN: CH2=CHCN) cluster anions, (AN)-n (2≤n≤9), were irradiated with a laser at photon energies of 1.17 and 2.33 eV, and mass spectra of fragment anions were observed by a time-of-flight mass spectrometer. The trimer and the hexamer anions, (AN)-3 and (AN)-6, were found to be produced dominantly by the photodissociation. The results revealed, in comparison with our previous results on the photoelectron spectra and collision-induced dissociation of AN cluster anions, that the parent anion (AN)-n (n≥3) consists of a polymerized cyclic trimer anion (AN)-3, a polymerized cyclic neutral trimer unit (AN)3 and AN molecule(s).

本文言語英語
ページ(範囲)423-427
ページ数5
ジャーナルChemical Physics Letters
260
3-4
DOI
出版ステータス出版済み - 9 27 1996
外部発表はい

All Science Journal Classification (ASJC) codes

  • Physics and Astronomy(all)
  • Physical and Theoretical Chemistry

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