Photoelectron spectroscopy of Co-n and product anions of Co-n with O2 and N2

Hiroyuki Yoshida, Akira Terasaki, Tamotsu Kondow

研究成果: Contribution to journalArticle査読

3 被引用数 (Scopus)

抄録

The photoelectron spectra of Co-n (3 ≤ n ≤ 70), ComN- and ComO- (3 ≤ m ≤ 6) were measured by a XeCl excimer laser (4.025 eV). Also the reactivities of Co-n with O2 and CO were measured. A clear distinction between the cluster size of n ≤ 6 and that of n ≥ 7 was observed both in the photoelectron spectra and in the reactivities. (i) In the size range above n = 7, the electron affinities of the cobalt clusters determined by the photoelectron spectra are linearly dependent on the reciprocal of the cluster radius, but below this size they deviate from this relation. (ii) The reactivity of Co-n with O2 in the size range below n = 6 is higher than that above n = 7. However, the reactivity with CO in the size range below n = 6 is extremely lower than that above n = 7. These findings suggest that a transition of electronic structure in size dependence, which is correlated with the reactivity, occurs at n ≃ 7.

本文言語英語
ページ(範囲)667-670
ページ数4
ジャーナルSurface Review and Letters
3
1
出版ステータス出版済み - 2 1 1996
外部発表はい

All Science Journal Classification (ASJC) codes

  • 凝縮系物理学
  • 表面および界面
  • 表面、皮膜および薄膜
  • 材料化学

フィンガープリント

「Photoelectron spectroscopy of Co<sup>-</sup><sub>n</sub> and product anions of Co<sup>-</sup><sub>n</sub> with O<sub>2</sub> and N<sub>2</sub>」の研究トピックを掘り下げます。これらがまとまってユニークなフィンガープリントを構成します。

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