Photoinduced crystallization in ionic liquids: Photodimerization-induced equilibrium shift and crystal patterning

    研究成果: Contribution to journalArticle査読

    7 被引用数 (Scopus)

    抄録

    An ionic liquid (IL) composed of 9-anthracenecarboxylate anion and ammonium cation possessing three diethylene glycol chains shows phototriggered dimerization of anthracence chromophores. It causes segregation and crystallization of protonated 9-anthracenecarboxylic acid dimer, which is associated with the concurrent liberation of the free amine in the IL. This work provides a new molecular design for photoresponsive ILs, whose first application for site-selective photopatterning is demonstrated.

    本文言語英語
    ページ(範囲)908-910
    ページ数3
    ジャーナルChemistry Letters
    44
    7
    DOI
    出版ステータス出版済み - 2015

    All Science Journal Classification (ASJC) codes

    • 化学 (全般)

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