Photoinduced intramolecular electron transfer reactions in fullerene-phenothiazine linked compounds: Effects of magnetic field and spacer chain length

Hiroaki Yonemura, Masakazu Noda, Kazuya Hayashi, Hiromasa Tokudome, Shinya Moribe, Sunao Yamada

    研究成果: ジャーナルへの寄稿学術誌査読

    16 被引用数 (Scopus)

    抄録

    Spectroscopic and electrochemical properties of two fullerene(C60)-phenothiazine(PH) linked compounds with different spacer chain length have been compared in benzonitrile (polar solvent) and in benzene (non-polar solvent). Transient absorption and fluorescence spectra indicated that photoinduced intramolecular electron transfer occurred in benzonitrile, but not in benzene. The results are due to solvent effect on energy levels of the photogenerated biradical. The driving forces for the electron transfer were determined by measuring the redox potentials of the C60 and PH moieties. Thermodynamic parameters for the electron transfer processes were evaluated and compared. In benzonitrile, the lifetime of the photo-generated biradical was very long, in spite of being around the top region in Marcus theory. The decay rate of the biradicals was retarded in the presence of magnetic fields. The decay rate constant decreased quickly with increasing the magnetic field and became constant above about 0.2T. The magnetic field effects verified that the triplet biradical was generated by the intramolecular electron transfer from PH to the triplet excited state of C60. The long lifetime is most probably ascribed to the spin multiplicities of the biradical.

    本文言語英語
    ページ(範囲)1395-1403
    ページ数9
    ジャーナルMolecular Physics
    100
    9
    DOI
    出版ステータス出版済み - 5月 10 2002

    !!!All Science Journal Classification (ASJC) codes

    • 生物理学
    • 分子生物学
    • 凝縮系物理学
    • 物理化学および理論化学

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