Photoinduced magnetic memory effect in an iron (II) spin-crossover complex

Hongwu Liu, Akira Fujishima, Osamu Sato

研究成果: Contribution to journalArticle査読

13 被引用数 (Scopus)

抄録

Magnetic memory effect in an iron (II) spin-crossover induced by illumination was studied. It was found that an Fe (II) spin-cross (SC) complex could be optically changed from the low spin (LS) to the high-spin (HS) state (LIESST). It was observed that a change in the molecular structure between the seven-coordinate HS and the six-coordinate LS forms took place during the thermal spin-state transition, along with a color variation from dark blue to bluish violet. The results show that the total HS fraction on both sites is greater than 50 percent for reverse LIESST (H→S) caused by illumination with 980 nm light.

本文言語英語
ページ(範囲)2295-2297
ページ数3
ジャーナルApplied Physics Letters
85
12
DOI
出版ステータス出版済み - 9 20 2004
外部発表はい

All Science Journal Classification (ASJC) codes

  • 物理学および天文学(その他)

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