Photoinduced metal-to-metal charge transfer toward single-chain magnet

Tao Liu, Yan Juan Zhang, Shinji Kanegawa, Osamu Sato

研究成果: Contribution to journalArticle査読

153 被引用数 (Scopus)

抄録

Single-chain magnets (SCMs) that exhibit slow relaxation of their magnetization are attracting considerable attention. To tune the properties of such materials with external stimuli such as light, heat, and pressure is a challenge. Through the exploitation of light and heat induced transformation between diamagnetic FeIILS (μ-CN)CoIIILS (LS = low spin) units and paramagnetic FeIIILS (μ-CN)CoIIHS (HS = high spin) units, we show the photoswitched transformation from a paramagnetic state to an antiferromagnetic ordered SCM state and the thermally induced reverse transformation, thus providing an effective way to control the spin topology of the SCM via light or a thermally induced metal-to-metal charge transfer.

本文言語英語
ページ(範囲)8250-8251
ページ数2
ジャーナルJournal of the American Chemical Society
132
24
DOI
出版ステータス出版済み - 6 23 2010

All Science Journal Classification (ASJC) codes

  • 化学 (全般)
  • 触媒
  • 生化学
  • コロイド化学および表面化学

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