Photon-absorbing charge-bridging states in organic bulk heterojunctions consisting of diketopyrrolopyrrole derivatives and PCBM

Mikiya Fujii, Woong Shin, Takuma Yasuda, Koichi Yamashita

研究成果: ジャーナルへの寄稿記事

7 引用 (Scopus)

抄録

We have investigated the photo- and electrochemical properties of five diketopyrrolopyrrole (DPP) derivatives both experimentally and theoretically. In the experimental study, we found that a blend of a DPP derivative named D2 and phenyl-C61-butyric acid methyl ester (PCBM) exhibits the highest internal quantum efficiency (IQE) and power convergence efficiency (PCE) among the five derivatives investigated. In the theoretical study, we found that the open-circuit voltage can be estimated from the difference between the energy gap of frontier orbitals and the voltage loss and that the latter is suppressed when the IQE is large. Then, to investigate the factors that influence the IQE, investigations on charge recombination, hole transfer, and charge transfer induced by photoabsorption were conducted for the complexes of each DPP derivative and PCBM. It was found that D2/PCBM exhibits the largest charge-bridging upon photoabsorption, which leads to the highest IQE and PCE among the five DPP derivatives.

元の言語英語
ページ(範囲)9514-9523
ページ数10
ジャーナルPhysical Chemistry Chemical Physics
18
発行部数14
DOI
出版物ステータス出版済み - 4 14 2016

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Butyric Acid
butyric acid
Heterojunctions
heterojunctions
quantum efficiency
esters
Esters
Quantum efficiency
Photons
Derivatives
photons
photoabsorption
open circuit voltage
Open circuit voltage
Electrochemical properties
charge transfer
Charge transfer
Energy gap
orbitals
electric potential

All Science Journal Classification (ASJC) codes

  • Physics and Astronomy(all)
  • Physical and Theoretical Chemistry

これを引用

Photon-absorbing charge-bridging states in organic bulk heterojunctions consisting of diketopyrrolopyrrole derivatives and PCBM. / Fujii, Mikiya; Shin, Woong; Yasuda, Takuma; Yamashita, Koichi.

:: Physical Chemistry Chemical Physics, 巻 18, 番号 14, 14.04.2016, p. 9514-9523.

研究成果: ジャーナルへの寄稿記事

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N2 - We have investigated the photo- and electrochemical properties of five diketopyrrolopyrrole (DPP) derivatives both experimentally and theoretically. In the experimental study, we found that a blend of a DPP derivative named D2 and phenyl-C61-butyric acid methyl ester (PCBM) exhibits the highest internal quantum efficiency (IQE) and power convergence efficiency (PCE) among the five derivatives investigated. In the theoretical study, we found that the open-circuit voltage can be estimated from the difference between the energy gap of frontier orbitals and the voltage loss and that the latter is suppressed when the IQE is large. Then, to investigate the factors that influence the IQE, investigations on charge recombination, hole transfer, and charge transfer induced by photoabsorption were conducted for the complexes of each DPP derivative and PCBM. It was found that D2/PCBM exhibits the largest charge-bridging upon photoabsorption, which leads to the highest IQE and PCE among the five DPP derivatives.

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