Photoresponsive Crown Ethers

Seiji Shinkai, Osamu Manabe

研究成果: Contribution to journalArticle

2 引用 (Scopus)

抜粋

A photoresponsive crown ether which combines within a molecule both a crown ether and a photoisomerizable functional group changes the conformation of the crown ring in response to photoirradiation. Thus, many chemical and physical functions of the crown ether family can be controlled by on-off light switch. The syntheses and the functions (ion extraction, ion transport, etc.) of following photoresponsive crown ethers are described: azobenzene-bridged crown ethers, crown ethers containing azobenzene as a ring member, azobis(benzocrown ether)s, and anthracene-containing crown ethers. In relation to the cis-trans isomerism of azobenzene, the mechanism of thermal cis-to-trans isomerization is discussed.

元の言語英語
ページ(範囲)92-101
ページ数10
ジャーナルJournal of Synthetic Organic Chemistry, Japan
40
発行部数2
DOI
出版物ステータス出版済み - 1 1982
外部発表Yes

All Science Journal Classification (ASJC) codes

  • Organic Chemistry

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