Planar chiral dialkoxysilane: Introduction of inherent chirality and high reactivity in conventional achiral alkene

Katsuhiko Tomooka, Shouji Miyasaka, Shougo Motomura, Kazunobu Igawa

研究成果: ジャーナルへの寄稿記事

9 引用 (Scopus)

抜粋

A simple eight-membered dialkoxysilane (E)-1 prepared from 2-pentene-1,5-diol, showed remarkably stable planar chirality along with high reactivity toward epoxidation, Diels-Alder reaction, and cycloaddition reaction with azide. Enriching alkenes: A simple eight-membered dialkoxysilane, prepared from 2-pentene-1,5-diol, shows remarkably stable planar chirality along with quite a high reactivity in epoxidation reactions, Diels-Alder reactions, and in cycloaddition reactions with azide (see scheme).

元の言語英語
ページ(範囲)7598-7602
ページ数5
ジャーナルChemistry - A European Journal
20
発行部数25
DOI
出版物ステータス出版済み - 6 16 2014

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All Science Journal Classification (ASJC) codes

  • Catalysis
  • Organic Chemistry

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