Poly(para-phenylene) with the end structure of CH2-(C6H4)n-H provides nearly zero band gaps in long chains with n>6

研究成果: Contribution to journalArticle査読

1 被引用数 (Scopus)

抄録

It was demonstrated from the molecular orbital theory that CH2-(C6H4)n- in which at least one H atom on the end of poly (para-phenylene) (PPP) is replaced by CH2 group of the chain, provides nearly zero band gaps in the long chains with n>6. This behavior was explained by the band overlap leading to metallic characteristics from the perspective of the intermolecular-interaction between ethylene units in the oligomer.

本文言語英語
論文番号193104
ページ(範囲)1931041-1931044
ページ数4
ジャーナルPhysical Review B - Condensed Matter and Materials Physics
66
19
出版ステータス出版済み - 11 15 2002
外部発表はい

All Science Journal Classification (ASJC) codes

  • 電子材料、光学材料、および磁性材料
  • 凝縮系物理学

フィンガープリント

「Poly(para-phenylene) with the end structure of CH<sub>2</sub>-(C<sub>6</sub>H<sub>4</sub>)<sub>n</sub>-H provides nearly zero band gaps in long chains with n>6」の研究トピックを掘り下げます。これらがまとまってユニークなフィンガープリントを構成します。

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