Potentiometric flow-injection determination of trace chlorine based on its redox reaction with an iron(III)/iron(II) buffer

Nobuhiko Ishibashi, Toshihiko Imato, Hiroki Ohura, Sumio Yamasaki

研究成果: ジャーナルへの寄稿記事

24 引用 (Scopus)

抄録

A very sensitive and rapid potentiometric determination of trace chlorine in water is described. The method is based on the transient potential changes which appears during the reduction of dissolved chlorin with an iron(III)/iron(II) potential buffer containing chloride and sulfuric acid. The sample is injected into a water carrier stream and merged with a stream of this potential buffer solution; chlorine is reduced during passage through a short reaction coil. The potential change from the baseline is measured with a flow-through ORP (oxidation-reduction potential) electrode. Potential changes (peak heights) are proportional to chlorine concentrations from 10-7 M to 10-5 M. The detection limit is 5 × 10-8 M (3.5 μgl-1 as Cl2). The sample throughput is 45 h-1. Reproducibility is in the range 2.5-1.1%. Results for potable water agree with those obtained by the o-tolidine method.

元の言語英語
ページ(範囲)349-357
ページ数9
ジャーナルAnalytica Chimica Acta
214
発行部数C
DOI
出版物ステータス出版済み - 1 1 1988

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Redox reactions
Chlorine
Oxidation-Reduction
chlorine
Buffers
Iron
iron
Injections
chlorin
Water
Drinking Water
sulfuric acid
Limit of Detection
Chlorides
Electrodes
electrode
drinking water
chloride
Throughput
water

All Science Journal Classification (ASJC) codes

  • Analytical Chemistry
  • Biochemistry
  • Environmental Chemistry
  • Spectroscopy

これを引用

Potentiometric flow-injection determination of trace chlorine based on its redox reaction with an iron(III)/iron(II) buffer. / Ishibashi, Nobuhiko; Imato, Toshihiko; Ohura, Hiroki; Yamasaki, Sumio.

:: Analytica Chimica Acta, 巻 214, 番号 C, 01.01.1988, p. 349-357.

研究成果: ジャーナルへの寄稿記事

Ishibashi, Nobuhiko ; Imato, Toshihiko ; Ohura, Hiroki ; Yamasaki, Sumio. / Potentiometric flow-injection determination of trace chlorine based on its redox reaction with an iron(III)/iron(II) buffer. :: Analytica Chimica Acta. 1988 ; 巻 214, 番号 C. pp. 349-357.
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abstract = "A very sensitive and rapid potentiometric determination of trace chlorine in water is described. The method is based on the transient potential changes which appears during the reduction of dissolved chlorin with an iron(III)/iron(II) potential buffer containing chloride and sulfuric acid. The sample is injected into a water carrier stream and merged with a stream of this potential buffer solution; chlorine is reduced during passage through a short reaction coil. The potential change from the baseline is measured with a flow-through ORP (oxidation-reduction potential) electrode. Potential changes (peak heights) are proportional to chlorine concentrations from 10-7 M to 10-5 M. The detection limit is 5 × 10-8 M (3.5 μgl-1 as Cl2). The sample throughput is 45 h-1. Reproducibility is in the range 2.5-1.1{\%}. Results for potable water agree with those obtained by the o-tolidine method.",
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