Powder XRD and solid-state2H-NMR studies on RAP-protected palladium nanoparticle (RAP = rubeanic-acid polymer)

M. Fujishima, M. Yamauchi, R. Ikeda, T. Kubo, K. Nakasuji, H. Kitagawa

研究成果: 著書/レポートタイプへの貢献会議での発言

1 引用 (Scopus)

抜粋

This study reports hydrogen absorption property of newly-synthesized RAP (rubeanic-acid polymer)-protected palladium nanoparticle (RAP-Pd). From powder X-ray diffraction measurements, the lattice constant of Pd nanoparticle was revealed to increase by 0.11 Å under 600 Torr hydrogen gas condition at room temperature, indicating that the hydrogen absorption occurs in the Pd nanoparticle. Solid-state2H-NMR spectrum under deuterium gas showed that three different components exist in RAP-Pd, which are derived from imino group, terminal amino group in the RAP and absorbed deuterium atom inside the Pd nanoparticle. This result gives an expectation of the hydrogen absorption in RAP itself.

元の言語英語
ホスト出版物のタイトルScience and Technology of Hybrid Materials
編集者Cheng-Jun Sun, Gan-Moog Chow, Lynn Kurihara, Lawrence Kabacoff, Manoj Gupta, Jun Ding
出版者Trans Tech Publications Ltd
ページ107-110
ページ数4
ISBN(印刷物)9783908451181
DOI
出版物ステータス出版済み - 1 1 2006
イベントSymposium S Science and Technology of Hybrid Materials, 2005: 3rd International Conference on Materials for Advanced Technologies, ICMAT 2005 and International Union of Materials Research Societies-9th International Conference on Advanced Materials, IUMRS-ICAM 2005 - Singapore, シンガポール
継続期間: 7 3 20057 8 2005

出版物シリーズ

名前Solid State Phenomena
111
ISSN(電子版)1662-9779

その他

その他Symposium S Science and Technology of Hybrid Materials, 2005: 3rd International Conference on Materials for Advanced Technologies, ICMAT 2005 and International Union of Materials Research Societies-9th International Conference on Advanced Materials, IUMRS-ICAM 2005
シンガポール
Singapore
期間7/3/057/8/05

    フィンガープリント

All Science Journal Classification (ASJC) codes

  • Atomic and Molecular Physics, and Optics
  • Materials Science(all)
  • Condensed Matter Physics

これを引用

Fujishima, M., Yamauchi, M., Ikeda, R., Kubo, T., Nakasuji, K., & Kitagawa, H. (2006). Powder XRD and solid-state2H-NMR studies on RAP-protected palladium nanoparticle (RAP = rubeanic-acid polymer). : C-J. Sun, G-M. Chow, L. Kurihara, L. Kabacoff, M. Gupta, & J. Ding (版), Science and Technology of Hybrid Materials (pp. 107-110). (Solid State Phenomena; 巻数 111). Trans Tech Publications Ltd. https://doi.org/10.4028/www.scientific.net/SSP.111.107