Preparation and optical resolution of a new helical lactone carrying the 2,8-dioxabicyclo[3.3.0]octane ring system

Makoto Yamaye, Yusuke Ikeda, Namiko Cho, Yoshinori Miura, Tetsutaro Yoshinaga, Katsuya Mukae, Toshiaki Tsuru

研究成果: Contribution to journalArticle査読

4 被引用数 (Scopus)

抄録

A new overcrowded lactone (3) carrying the 2,8-dioxabicyclo[3.3.0]octane ring system was prepared by a simple treatment of tetraol (1) (prepared from 2,7-dihydroxynaphthalene and glyoxal) with 3,5-xylenol, and readily resolved into its enantiomers having a specific rotation of >800Θ (absolute value). A preliminary experiment demonstrated that 3 would be a promising resolving agent.

本文言語英語
ページ(範囲)137-143
ページ数7
ジャーナルHeterocycles
63
1
DOI
出版ステータス出版済み - 1 1 2004

All Science Journal Classification (ASJC) codes

  • 分析化学
  • 薬理学
  • 有機化学

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