抄録
In this study, a new tetrathiafulvalene-functionalized phenanthroline ligand (TTF-phen) and a mononuclear cobalt(II) complex with a redox active 3,6-di-tert-butylsemiquinonato (3,6-dtsq) ligand was synthesized. Magnetic measurementsand IR spectroscopy suggested that the Co complex [Co(3,6- dtsq)2(TTF-phen)] exhibited thermally induced valence tautomerismin the temperature range 130400 K. This complex is the first example of a valence tautomeric complex with a TTFfunctionalized ligand.
本文言語 | 英語 |
---|---|
ページ(範囲) | 700-702 |
ページ数 | 3 |
ジャーナル | Chemistry Letters |
巻 | 42 |
号 | 7 |
DOI | |
出版ステータス | 出版済み - 2013 |
!!!All Science Journal Classification (ASJC) codes
- 化学 (全般)