Preparation and valence tautomeric behavior of a cobaltdioxolene complex with a new TTF-functionalized phenanthroline Ligand

Shinji Kanegawa, Soonchul Kang, Osamu Sato

研究成果: Contribution to journalArticle査読

4 被引用数 (Scopus)

抄録

In this study, a new tetrathiafulvalene-functionalized phenanthroline ligand (TTF-phen) and a mononuclear cobalt(II) complex with a redox active 3,6-di-tert-butylsemiquinonato (3,6-dtsq) ligand was synthesized. Magnetic measurementsand IR spectroscopy suggested that the Co complex [Co(3,6- dtsq)2(TTF-phen)] exhibited thermally induced valence tautomerismin the temperature range 130400 K. This complex is the first example of a valence tautomeric complex with a TTFfunctionalized ligand.

本文言語英語
ページ(範囲)700-702
ページ数3
ジャーナルChemistry Letters
42
7
DOI
出版ステータス出版済み - 2013

All Science Journal Classification (ASJC) codes

  • 化学 (全般)

フィンガープリント

「Preparation and valence tautomeric behavior of a cobaltdioxolene complex with a new TTF-functionalized phenanthroline Ligand」の研究トピックを掘り下げます。これらがまとまってユニークなフィンガープリントを構成します。

引用スタイル