TY - JOUR
T1 - Preparation of glycidyl celluloses from completely allylated methylcellulose and tri‐O‐allylcellulose
AU - Kondo, Tetsuo
AU - Ishizu, Atsushi
AU - Nakano, Junzo
PY - 1989/5/20
Y1 - 1989/5/20
N2 - Glycidyl celluloses were prepared from completely allylated methylcellulose and tri‐O‐allylcellulose with m‐chloroperbenzoic acid in homogeneous chloroform solutions. The degrees of substitution (DS) by epoxy groups were 0.60 and 1.33 for the products prepared from allylated methylcellulose and tri‐O‐allylcellulose, respectively. They were soluble in not only many organic solvents, but also methanol‐water mixtures [more than 70% (v/v)]. These products were characterized by infrared spectroscopy (IR), 13C‐NMR spectroscopy, and gel permeation chromatography (GPC).
AB - Glycidyl celluloses were prepared from completely allylated methylcellulose and tri‐O‐allylcellulose with m‐chloroperbenzoic acid in homogeneous chloroform solutions. The degrees of substitution (DS) by epoxy groups were 0.60 and 1.33 for the products prepared from allylated methylcellulose and tri‐O‐allylcellulose, respectively. They were soluble in not only many organic solvents, but also methanol‐water mixtures [more than 70% (v/v)]. These products were characterized by infrared spectroscopy (IR), 13C‐NMR spectroscopy, and gel permeation chromatography (GPC).
UR - http://www.scopus.com/inward/record.url?scp=0024657130&partnerID=8YFLogxK
UR - http://www.scopus.com/inward/citedby.url?scp=0024657130&partnerID=8YFLogxK
U2 - 10.1002/app.1989.070371017
DO - 10.1002/app.1989.070371017
M3 - Article
AN - SCOPUS:0024657130
VL - 37
SP - 3003
EP - 3009
JO - Journal of Applied Polymer Science
JF - Journal of Applied Polymer Science
SN - 0021-8995
IS - 10
ER -