Preparation of Novel Ruthenlum(IV) Complexes (η5-C5(CH3)5)Ru(η3-allyl)X2 and (η5-C5H5)Ru(η3-allyl)X2 by Oxidative Addition of Allylic Halides to Ruthenlum(II) Precursors

Hideo Nagashima, Katsunori Mukai, Kenji Itoh

研究成果: ジャーナルへの寄稿記事

39 引用 (Scopus)

抄録

Oxidative addition of allylic halides to ruthenium(II) carbonyl complexes Cp'Ru(CO)2X and CpRu-(CO)2X [Cp' = η5-C5(CH3)5; Cp = η5-C5H5; X = Br, Cl] resulted in the formation of novel Ru(IV) complexes Cp'Ru(η3-allyl)X2 and CpRu(η3-allyl)X2. Reaction of the resulting ruthenium(IV) allyl complexes with CO did not lead to incorporation of CO into the allylic moiety but gave rise to reductive elimination of the allylic halides from the Ru(IV) metal center to afford the ruthenium(II) carbonyl complexes Cp'-and CpRu(CO)2X.

元の言語英語
ページ(範囲)1314-1315
ページ数2
ジャーナルOrganometallics
3
発行部数8
DOI
出版物ステータス出版済み - 1 1 1984

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Carbon Monoxide
ruthenium
halides
Ruthenium
preparation
elimination
metals
Metals

All Science Journal Classification (ASJC) codes

  • Physical and Theoretical Chemistry
  • Organic Chemistry
  • Inorganic Chemistry

これを引用

Preparation of Novel Ruthenlum(IV) Complexes (η5-C5(CH3)5)Ru(η3-allyl)X2 and (η5-C5H5)Ru(η3-allyl)X2 by Oxidative Addition of Allylic Halides to Ruthenlum(II) Precursors. / Nagashima, Hideo; Mukai, Katsunori; Itoh, Kenji.

:: Organometallics, 巻 3, 番号 8, 01.01.1984, p. 1314-1315.

研究成果: ジャーナルへの寄稿記事

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title = "Preparation of Novel Ruthenlum(IV) Complexes (η5-C5(CH3)5)Ru(η3-allyl)X2 and (η5-C5H5)Ru(η3-allyl)X2 by Oxidative Addition of Allylic Halides to Ruthenlum(II) Precursors",
abstract = "Oxidative addition of allylic halides to ruthenium(II) carbonyl complexes Cp'Ru(CO)2X and CpRu-(CO)2X [Cp' = η5-C5(CH3)5; Cp = η5-C5H5; X = Br, Cl] resulted in the formation of novel Ru(IV) complexes Cp'Ru(η3-allyl)X2 and CpRu(η3-allyl)X2. Reaction of the resulting ruthenium(IV) allyl complexes with CO did not lead to incorporation of CO into the allylic moiety but gave rise to reductive elimination of the allylic halides from the Ru(IV) metal center to afford the ruthenium(II) carbonyl complexes Cp'-and CpRu(CO)2X.",
author = "Hideo Nagashima and Katsunori Mukai and Kenji Itoh",
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T1 - Preparation of Novel Ruthenlum(IV) Complexes (η5-C5(CH3)5)Ru(η3-allyl)X2 and (η5-C5H5)Ru(η3-allyl)X2 by Oxidative Addition of Allylic Halides to Ruthenlum(II) Precursors

AU - Nagashima, Hideo

AU - Mukai, Katsunori

AU - Itoh, Kenji

PY - 1984/1/1

Y1 - 1984/1/1

N2 - Oxidative addition of allylic halides to ruthenium(II) carbonyl complexes Cp'Ru(CO)2X and CpRu-(CO)2X [Cp' = η5-C5(CH3)5; Cp = η5-C5H5; X = Br, Cl] resulted in the formation of novel Ru(IV) complexes Cp'Ru(η3-allyl)X2 and CpRu(η3-allyl)X2. Reaction of the resulting ruthenium(IV) allyl complexes with CO did not lead to incorporation of CO into the allylic moiety but gave rise to reductive elimination of the allylic halides from the Ru(IV) metal center to afford the ruthenium(II) carbonyl complexes Cp'-and CpRu(CO)2X.

AB - Oxidative addition of allylic halides to ruthenium(II) carbonyl complexes Cp'Ru(CO)2X and CpRu-(CO)2X [Cp' = η5-C5(CH3)5; Cp = η5-C5H5; X = Br, Cl] resulted in the formation of novel Ru(IV) complexes Cp'Ru(η3-allyl)X2 and CpRu(η3-allyl)X2. Reaction of the resulting ruthenium(IV) allyl complexes with CO did not lead to incorporation of CO into the allylic moiety but gave rise to reductive elimination of the allylic halides from the Ru(IV) metal center to afford the ruthenium(II) carbonyl complexes Cp'-and CpRu(CO)2X.

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