Preparation of Novel Ruthenlum(IV) Complexes (η5-C5(CH3)5)Ru(η3-allyl)X2 and (η5-C5H5)Ru(η3-allyl)X2 by Oxidative Addition of Allylic Halides to Ruthenlum(II) Precursors

Hldeo Nagashima, Katsunori Mukai, Kenji Itoh

研究成果: Contribution to journalArticle査読

39 被引用数 (Scopus)

抄録

Oxidative addition of allylic halides to ruthenium(II) carbonyl complexes Cp'Ru(CO)2X and CpRu-(CO)2X [Cp' = η5-C5(CH3)5; Cp = η5-C5H5; X = Br, Cl] resulted in the formation of novel Ru(IV) complexes Cp'Ru(η3-allyl)X2 and CpRu(η3-allyl)X2. Reaction of the resulting ruthenium(IV) allyl complexes with CO did not lead to incorporation of CO into the allylic moiety but gave rise to reductive elimination of the allylic halides from the Ru(IV) metal center to afford the ruthenium(II) carbonyl complexes Cp'-and CpRu(CO)2X.

本文言語英語
ページ(範囲)1314-1315
ページ数2
ジャーナルOrganometallics
3
8
DOI
出版ステータス出版済み - 4 1984
外部発表はい

All Science Journal Classification (ASJC) codes

  • 物理化学および理論化学
  • 有機化学
  • 無機化学

フィンガープリント

「Preparation of Novel Ruthenlum(IV) Complexes (η<sup>5</sup>-C<sub>5</sub>(CH<sub>3</sub>)<sub>5</sub>)Ru(η<sup>3</sup>-allyl)X<sub>2</sub> and (η<sup>5</sup>-C<sub>5</sub>H<sub>5</sub>)Ru(η<sup>3</sup>-allyl)X<sub>2</sub> by Oxidative Addition of Allylic Halides to Ruthenlum(II) Precursors」の研究トピックを掘り下げます。これらがまとまってユニークなフィンガープリントを構成します。

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