Proton-coupled electron shuttling in a covalently linked ruthenium-copper heterodinuclear complex

Tomoya Ishizuka, Kengo Tobita, Yuichi Yano, Yoshihito Shiota, Kazunari Yoshizawa, Shunichi Fukuzumi, Takahiko Kojima

研究成果: Contribution to journalArticle査読

13 被引用数 (Scopus)

抄録

A heterodinuclear complex based on a RuII-TPA [TPA = tris(2-pyridylmethyl)amine] complex having a peripheral CuII (bpy)2 (bpy = 2,2'-bipyridine) group bonded through an amide linkage displayed reversible intramolecular electron transfer between the Ru and Cu complex units that can be controlled by protonation and deprotonation of the bridging amide moiety.

本文言語英語
ページ(範囲)18570-18573
ページ数4
ジャーナルJournal of the American Chemical Society
133
46
DOI
出版ステータス出版済み - 11 23 2011

All Science Journal Classification (ASJC) codes

  • Catalysis
  • Chemistry(all)
  • Biochemistry
  • Colloid and Surface Chemistry

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