Proton-coupled electron shuttling in a covalently linked ruthenium-copper heterodinuclear complex

Tomoya Ishizuka, Kengo Tobita, Yuichi Yano, Yoshihito Shiota, Kazunari Yoshizawa, Shunichi Fukuzumi, Takahiko Kojima

研究成果: Contribution to journalArticle

13 引用 (Scopus)

抜粋

A heterodinuclear complex based on a RuII-TPA [TPA = tris(2-pyridylmethyl)amine] complex having a peripheral CuII (bpy)2 (bpy = 2,2'-bipyridine) group bonded through an amide linkage displayed reversible intramolecular electron transfer between the Ru and Cu complex units that can be controlled by protonation and deprotonation of the bridging amide moiety.

元の言語英語
ページ(範囲)18570-18573
ページ数4
ジャーナルJournal of the American Chemical Society
133
発行部数46
DOI
出版物ステータス出版済み - 11 23 2011

All Science Journal Classification (ASJC) codes

  • Catalysis
  • Chemistry(all)
  • Biochemistry
  • Colloid and Surface Chemistry

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