Pyridyl-anchored type bodipy sensitizer-tio2 photocatalyst for enhanced visible light-driven photocatalytic hydrogen production

研究成果: Contribution to journalArticle査読

1 被引用数 (Scopus)

抄録

Dye-sensitized photocatalytic hydrogen production using a boron-dipyrromethene (BODIPY) organic material having a pyridyl group at the anchor site was investigated. Phenyl, carbazole, and phenothiazine derivatives were introduced into BODIPY dyes, and their photocatalytic activities were examined. Identification was performed by nuclear magnetic resonance (NMR), infrared (IR), mass (MS) spectra, and absorption spectra, and catalyst evaluation was performed by using visible-light irradiation and photocatalytic hydrogen production and photocurrent. These dyes have strong absorption at 600–700 nm, suggesting that they are promising as photosensitizers. When the photocatalytic activity was examined, stable catalytic performance was demonstrated, and the activity of the Pt-TiO2 photocatalyst carrying a dye having a carbazole group was 249 μmol/gcat·h. Photocurrent measurements suggest that dye-sensitized photocatalytic activity is occurring. This result suggests that BODIPY organic materials with pyridyl groups as anchor sites are useful as novel dye-sensitized photocatalysts.

本文言語英語
論文番号535
ジャーナルCatalysts
10
5
DOI
出版ステータス出版済み - 5 2020

All Science Journal Classification (ASJC) codes

  • 触媒
  • 物理化学および理論化学

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