Radical cyclocopolymerization of divinyl ether derivatives with maleic anhydride. The structure determination of the alternating copolymers by 13C-NMR spectroscopy

Toshimitsu Mitsuo, Toyoki Kunitake

研究成果: ジャーナルへの寄稿記事

4 引用 (Scopus)

抄録

Radical copolymerizations of cis-propenyl vinyl ether, 2-methylpropenyl vinyl ether and cis-dipropenyl ether with maleic anhydride were carried out, and completely cyclized, and alternating copolymers were obtained with the 1: 2 composition of divinyl ethers and maleic anhydride. 13C-NMR spectroscopic data indicated that the polymers contained in common the bicyclic unit composed of one molecule of each monomer and the maleic anhydride unit. The bicyclic unit was characterized by the cis junction and the trans ring closure, and the maleic anhydride unit was formed by trans opening of the double bond. Introduction of methyl substituents do not appear to affect the polymer structure, though assignments become less definite.

元の言語英語
ページ(範囲)671-678
ページ数8
ジャーナルPolymer Journal
13
発行部数7
DOI
出版物ステータス出版済み - 7 1981

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Maleic Anhydrides
Maleic anhydride
Nuclear magnetic resonance spectroscopy
Ethers
Copolymers
Derivatives
Pyran Copolymer
Polymers
Ether
Copolymerization
Monomers
Nuclear magnetic resonance
Molecules
Chemical analysis
vinyl ether

All Science Journal Classification (ASJC) codes

  • Polymers and Plastics
  • Materials Chemistry

これを引用

Radical cyclocopolymerization of divinyl ether derivatives with maleic anhydride. The structure determination of the alternating copolymers by 13C-NMR spectroscopy. / Mitsuo, Toshimitsu; Kunitake, Toyoki.

:: Polymer Journal, 巻 13, 番号 7, 07.1981, p. 671-678.

研究成果: ジャーナルへの寄稿記事

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AB - Radical copolymerizations of cis-propenyl vinyl ether, 2-methylpropenyl vinyl ether and cis-dipropenyl ether with maleic anhydride were carried out, and completely cyclized, and alternating copolymers were obtained with the 1: 2 composition of divinyl ethers and maleic anhydride. 13C-NMR spectroscopic data indicated that the polymers contained in common the bicyclic unit composed of one molecule of each monomer and the maleic anhydride unit. The bicyclic unit was characterized by the cis junction and the trans ring closure, and the maleic anhydride unit was formed by trans opening of the double bond. Introduction of methyl substituents do not appear to affect the polymer structure, though assignments become less definite.

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