Rapid coagulation of Langmuir-Blodgett mesoscopic bands on mica by monovalent ions

Masahito Sano, Ayumi Kamino, Seiji Shinkai

研究成果: Contribution to journalArticle査読

2 被引用数 (Scopus)


Langmuir-Blodgett films of 4-heptoxy-4'-carboxyazobenzene on mica transferred from pure water exhibit novel strip structures consisting of mono-molecular thick straight bands 80 nm wide and more than 100 μm long. To examine a possibility that these bands are self-organized structures of small monolayer clusters, the effects of monovalent ions are investigated. The monovalent ions caused the mesoscopic bands to coagulate. The fraction of coagulated bands was measured as a function of ion concentrations at pH 7.0 by atomic force microscopy. K+ and Cs+ are shown to interact with the mica surface strongly and destabilize the bands by developing the hydration force. Na+ and Li+ cause critical coagulation without destabilization and have the critical concentrations at 3.0 and 1.6 mM, respectively. UV-vis reflection spectroscopy demonstrates that no molecular reorientation deviating from an H-aggregate-like state occurs during coagulation. X-ray photoelectron spectroscopy was used to obtain an adsorption isotherm of Na+. A comparison with a model monolayer described by Poisson-Boltzmann-Stern theory shows that the unusually large Na+ binding occurs prior to the coagulation. A comment is made on the importance of the characteristically large perimeter regions of monolayer clusters making up the band.

ジャーナルJournal of Colloid And Interface Science
出版ステータス出版済み - 12 1 1999

All Science Journal Classification (ASJC) codes

  • 電子材料、光学材料、および磁性材料
  • 生体材料
  • 表面、皮膜および薄膜
  • コロイド化学および表面化学


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