抄録
Reactions of three kind of syringylglycerol-β -syringyl ether type model compounds under alkaline medium were investigated. Sinapyl alcohol and β -hydroxypropiosyringone were formed as phenyl propanoid moieties from syringylglycerol- β -{methyl-syringyl) ether 1 by the β -aryl ether cleavage under soda treatment, while only sinapyl alcohol was formed from syringylglycerol- β -syringyl ether 2. The formation of both two degradation products are quite interesting because there is no nucleophilic additives in soda liquor. A possible reaction mechanisms for the β -aryl cleavage of syringylglycerol-β -syringyl ether type is homolytical cleavage via quinone methide.
| 本文言語 | 英語 |
|---|---|
| ページ（範囲） | 25-42 |
| ページ数 | 18 |
| ジャーナル | Journal of Wood Chemistry and Technology |
| 巻 | 13 |
| 号 | 1 |
| DOI | |
| 出版ステータス | 出版済み - 3 1 1993 |
All Science Journal Classification (ASJC) codes
- Chemistry(all)
- Chemical Engineering(all)
- Materials Science(all)