Reactions involving fluoride ion part 43 1 oligomerisations of hexafluoro-1,3-butadiene and -but-2-yne

Richard D. Chambers, Shin Nishimura, Graham Sandford

研究成果: ジャーナルへの寄稿 › 記事

5 引用 (Scopus)

抄録

Oligomerisation of hexafluoro-1,3-butadiene (6) and hexafluorobut-2-yne (1) occur with tetrakis(dimethylamino)ethene (10), in the absence of a solvent. Hydrogen-terminated oligomers are obtained but in the presence of pentafluoropyridine (12) or tetrafluoropyrimidine (17), simple trapping products are obtained. It is concluded that the polymerisation of 6 occurs by very rapid rearrangement to 1, followed by polymerisation of the latter.

元の言語英語
ページ（範囲）63-68
ページ数6
ジャーナルJournal of Fluorine Chemistry
巻91
発行部数1
DOI
出版物ステータス出版済み - 8 10 1998
外部発表Yes

Fingerprint

butadiene
Fluorides
polymerization
fluoride
Polymerization
fluorides
Ions
Oligomerization
ion
oligomers
Oligomers
ethylene
trapping
Hydrogen
ions
hydrogen
products
1,3-butadiene
pentafluoropyridine
product

All Science Journal Classification (ASJC) codes

  • Biochemistry
  • Environmental Chemistry
  • Physical and Theoretical Chemistry
  • Organic Chemistry
  • Inorganic Chemistry

これを引用

Reactions involving fluoride ion part 43 1 oligomerisations of hexafluoro-1,3-butadiene and -but-2-yne. / Chambers, Richard D.; Nishimura, Shin; Sandford, Graham.

：: Journal of Fluorine Chemistry, 巻 91, 番号 1, 10.08.1998, p. 63-68.

研究成果: ジャーナルへの寄稿 › 記事

Chambers, RD, Nishimura, S & Sandford, G 1998, 'Reactions involving fluoride ion part 43 1 oligomerisations of hexafluoro-1,3-butadiene and -but-2-yne', Journal of Fluorine Chemistry, 巻. 91, 番号 1, pp. 63-68. https://doi.org/10.1016/S0022-1139(98)00213-9
Chambers RD, Nishimura S, Sandford G. Reactions involving fluoride ion part 43 1 oligomerisations of hexafluoro-1,3-butadiene and -but-2-yne. Journal of Fluorine Chemistry. 1998 8 10;91(1):63-68. https://doi.org/10.1016/S0022-1139(98)00213-9
Chambers, Richard D. ; Nishimura, Shin ; Sandford, Graham. / Reactions involving fluoride ion part 43 1 oligomerisations of hexafluoro-1,3-butadiene and -but-2-yne. ：: Journal of Fluorine Chemistry. 1998 ; 巻 91, 番号 1. pp. 63-68.
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AB - Oligomerisation of hexafluoro-1,3-butadiene (6) and hexafluorobut-2-yne (1) occur with tetrakis(dimethylamino)ethene (10), in the absence of a solvent. Hydrogen-terminated oligomers are obtained but in the presence of pentafluoropyridine (12) or tetrafluoropyrimidine (17), simple trapping products are obtained. It is concluded that the polymerisation of 6 occurs by very rapid rearrangement to 1, followed by polymerisation of the latter.

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