Reactions of 3,5-Dimethylbenzene-1,4-diazoöxide

Toyoki Kunitake, Charles C. Price

研究成果: ジャーナルへの寄稿記事

11 引用 (Scopus)

抄録

When 3,5-dimethylbenzene-1,4-diazoöxide was heated or irradiated with ultraviolet light in chlorinated hydrocarbons, the corresponding diazonium salt was obtained. When heated in chlorobenzene, the diazoöxide formed a mixture of hydroxybiphenyls and the diazonium salt. These results suggest the formation of an intermediate with free radical character. With boron trifluoride, a hydrated complex was obtained. The decomposition of the diazoöxide in tetrahydrofuran, thermally or photochemically, gave a one-to-one copolymer with the solvent. The product was crystalline under certain conditions. A cationic mechanism for this copolymerization is suggested.

元の言語英語
ページ(範囲)761-764
ページ数4
ジャーナルJournal of the American Chemical Society
85
発行部数6
DOI
出版物ステータス出版済み - 3 1 1963
外部発表Yes

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Diazoxide
Xylenes
Salts
Free radicals
Copolymerization
Chlorinated Hydrocarbons
Boron
Copolymers
Ultraviolet Rays
Crystalline materials
Decomposition
Free Radicals

All Science Journal Classification (ASJC) codes

  • Catalysis
  • Chemistry(all)
  • Biochemistry
  • Colloid and Surface Chemistry

これを引用

Reactions of 3,5-Dimethylbenzene-1,4-diazoöxide. / Kunitake, Toyoki; Price, Charles C.

:: Journal of the American Chemical Society, 巻 85, 番号 6, 01.03.1963, p. 761-764.

研究成果: ジャーナルへの寄稿記事

Kunitake, Toyoki ; Price, Charles C. / Reactions of 3,5-Dimethylbenzene-1,4-diazoöxide. :: Journal of the American Chemical Society. 1963 ; 巻 85, 番号 6. pp. 761-764.
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