Real-time observation of coil-to-globule transition in thermosensitive poly(N-isopropylacrylamide) brushes by quartz crystal microbalance

Annaka Masahiko, Chie Yahiro, Kenichi Nagase, Akihiko Kikuchi, Teruo Okano

研究成果: ジャーナルへの寄稿記事

44 引用 (Scopus)

抄録

Thermosensitive poly(N-isopropylacrylamide) (PNIPAm) brushes grafted on SiO 2 -coated quartz crystal surface were prepared by the surface initiated radical polymerization. Using X-ray photoelectron spectroscopy (XPS) and atomic force microscopy (AFM), about 50 nm thickness of PNIPAm brushes were successfully formed. Quartz crystal microbalance with dissipation (QCM-D) is employed to investigate the collapse and swelling behavior of the PNIPAm brushes in water in real time. Both frequency and dissipation of PNIPAm layer were found to change gradually over the temperature range 15-50 °C, indicating that the brushes undergo a continuous transition. This continuous change is attributed to the nonuniformity and stretching of PNIPAm brushes as well as the cooperativity between collapse and dehydration transition.

元の言語英語
ページ(範囲)5713-5720
ページ数8
ジャーナルpolymer
48
発行部数19
DOI
出版物ステータス出版済み - 9 10 2007

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Quartz crystal microbalances
Brushes
Quartz
Free radical polymerization
Dehydration
Stretching
Swelling
Atomic force microscopy
X ray photoelectron spectroscopy
poly-N-isopropylacrylamide
Crystals
Water
Temperature

All Science Journal Classification (ASJC) codes

  • Organic Chemistry
  • Polymers and Plastics
  • Materials Chemistry

これを引用

Real-time observation of coil-to-globule transition in thermosensitive poly(N-isopropylacrylamide) brushes by quartz crystal microbalance. / Masahiko, Annaka; Yahiro, Chie; Nagase, Kenichi; Kikuchi, Akihiko; Okano, Teruo.

:: polymer, 巻 48, 番号 19, 10.09.2007, p. 5713-5720.

研究成果: ジャーナルへの寄稿記事

Masahiko, Annaka ; Yahiro, Chie ; Nagase, Kenichi ; Kikuchi, Akihiko ; Okano, Teruo. / Real-time observation of coil-to-globule transition in thermosensitive poly(N-isopropylacrylamide) brushes by quartz crystal microbalance. :: polymer. 2007 ; 巻 48, 番号 19. pp. 5713-5720.
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abstract = "Thermosensitive poly(N-isopropylacrylamide) (PNIPAm) brushes grafted on SiO 2 -coated quartz crystal surface were prepared by the surface initiated radical polymerization. Using X-ray photoelectron spectroscopy (XPS) and atomic force microscopy (AFM), about 50 nm thickness of PNIPAm brushes were successfully formed. Quartz crystal microbalance with dissipation (QCM-D) is employed to investigate the collapse and swelling behavior of the PNIPAm brushes in water in real time. Both frequency and dissipation of PNIPAm layer were found to change gradually over the temperature range 15-50 °C, indicating that the brushes undergo a continuous transition. This continuous change is attributed to the nonuniformity and stretching of PNIPAm brushes as well as the cooperativity between collapse and dehydration transition.",
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AU - Masahiko, Annaka

AU - Yahiro, Chie

AU - Nagase, Kenichi

AU - Kikuchi, Akihiko

AU - Okano, Teruo

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