Recent progress of transition metal-catalysed regioselective C-H transformations based on noncovalent interactions

研究成果: ジャーナルへの寄稿総説査読

23 被引用数 (Scopus)

抄録

Transition metal-catalysed C-H transformations are powerful methods to obtain functionalised organic molecules from simple starting materials. Controlling regioselectivity is one of the most important issues in C-H transformations. Since the remarkable work by Murai and co-workers in 1993, many groups have reportedortho-selective C(sp2)-H transformations using directing group methods, in which interactions exist between substrates and catalytically active metal centres. In this review, new methodologies to achieve regioselective C-H transformations are described. In these methhodologies, noncovalent interactions between substrates and reagents or ligands of catalysts play important roles. In these cases, selective functionalization of remote C-H bonds, such asmeta- andpara-C-H bonds, can also be realized.

本文言語英語
ページ(範囲)4126-4134
ページ数9
ジャーナルOrganic and Biomolecular Chemistry
18
22
DOI
出版ステータス出版済み - 6月 14 2020

!!!All Science Journal Classification (ASJC) codes

  • 生化学
  • 物理化学および理論化学
  • 有機化学

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