Recent trends of asymmetric catalysis with water as a nucleophile

研究成果: Contribution to journalReview article査読

抄録

Utilizing water as a reagent is one of the important topics in synthetic organic chemistry due to unique features of water for green chemistry. This review outlines recent trends of asymmetric catalysis with water as a nucleophile, and mainly picks up transition metal catalyzed asymmetric allylic substitution with a water nucleophile and enantioselective O-H insertion of α-aryldiazoesters with water. Former one contains a mechanistically rare example that the enantioselection occurs in the nucleophilic attack of metal hydroxide species to electrophiles.

本文言語英語
ページ(範囲)949-950
ページ数2
ジャーナルYuki Gosei Kagaku Kyokaishi/Journal of Synthetic Organic Chemistry
70
9
DOI
出版ステータス出版済み - 2012
外部発表はい

All Science Journal Classification (ASJC) codes

  • Organic Chemistry

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