Refinement of the crystal structures of Cu6O8InCl and Cu6 O8Cu2Cl by neutron powder diffraction

Hiroshi Hayakawa, Etsuo Akiba, Shuitiro Ono, Hideo Ihara, Fujio Izumi, Hajime Asano

研究成果: Contribution to journalArticle査読

1 被引用数 (Scopus)

抄録

Two titled compounds which have different structures have been synthesized by heating mixtures of hydrates of copper (II) nitrate and copper (II) chloride, or indium nitrate. Their crystal structures have been refined by the Rietveld method using neutron powder diffraction data. Cu6O8InCl is a stoichiometric compound and has a murdochite-like structure. The crystal structure of Cu6O8Cu2Cl is essentially the same as that of Cu6O8InCl except Cu sites corresponding to the In sites. The cu atoms are not located at the In site (2b) in the cube, but distributed among 6 equivalent sites (24e) around the center of the oxygen cube with an occupation factor of about 0.29.

本文言語英語
ページ(範囲)745-751
ページ数7
ジャーナルNippon Seramikkusu Kyokai Gakujutsu Ronbunshi/Journal of the Ceramic Society of Japan
101
1175
DOI
出版ステータス出版済み - 1993
外部発表はい

All Science Journal Classification (ASJC) codes

  • セラミックおよび複合材料
  • 化学 (全般)
  • 凝縮系物理学
  • 材料化学

フィンガープリント

「Refinement of the crystal structures of Cu<sub>6</sub>O<sub>8</sub>InCl and Cu<sub>6</sub> O<sub>8</sub>Cu<sub>2</sub>Cl by neutron powder diffraction」の研究トピックを掘り下げます。これらがまとまってユニークなフィンガープリントを構成します。

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