Regio- and enantioselective monoborylation of alkenylsilanes catalyzed by an electron-donating chiral phosphine-Copper(I) complex

Koji Kubota, Eiji Yamamoto, Hajime Ito

研究成果: Contribution to journalArticle査読

33 被引用数 (Scopus)

抄録

An asymmetric monoborylation of alkenylsilanes catalyzed by a copper(I) complex with the chiral bisphosphine ligand BenzP* is reported. The reaction proceeded with excellent regioselectivity and high enantioselectivity to afford the corresponding optically active organoboronate esters with a stereogenic C-B bond containing a vicinal silyl group. The synthetic utility of the product is demonstrated through stepwise transformations to multifunctional optically active compounds in a stereospecific manner.

本文言語英語
ページ(範囲)3527-3531
ページ数5
ジャーナルAdvanced Synthesis and Catalysis
355
18
DOI
出版ステータス出版済み - 12 16 2013
外部発表はい

All Science Journal Classification (ASJC) codes

  • 触媒
  • 有機化学

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