Regioselective Functionalization of the Mesoporous Metal−Organic Framework, NU-1000, with Photo-Active Tris-(2,2′bipyridine)ruthenium(II)

Hisanori Nagatomi; Leighanne C. Gallington; Subhadip Goswami; Jiaxin Duan; Karena W. Chapman; Nobuhiro Yanai; Nobuo Kimizuka; Omar K. Farha; Joseph T. Hupp

doi:10.1021/acsomega.0c04823

Regioselective Functionalization of the Mesoporous Metal−Organic Framework, NU-1000, with Photo-Active Tris-(2,2′bipyridine)ruthenium(II)

Hisanori Nagatomi, Leighanne C. Gallington, Subhadip Goswami, Jiaxin Duan, Karena W. Chapman, Nobuhiro Yanai, Nobuo Kimizuka, Omar K. Farha, Joseph T. Hupp

研究成果: ジャーナルへの寄稿 › 学術誌 › 査読

8 被引用数 (Scopus)

抄録

Solvent-assisted ligand incorporation is an excellent method for the post-synthetic functionalization of Zr-based metal−organic frameworks (MOFs), as carboxylate-derivative functionalities readily coordinate to the Zr₆ nodes by displacing node-based aqua and terminal hydroxo ligands. In this study, a photocatalytically active ruthenium complex Ru^II(bpy)₂(dcbpy), that is, bis-(2,2′-bipyridine)-(4,4′-dicarboxy-2,2′-bipyridine)ruthenium, was installed in the mono-protonated (carboxylic acid) form within NU-1000 via SALI. Crystallographic information regarding the siting of the ruthenium complex within the MOF pores is obtained by difference envelope density analysis. The ruthenium-functionalized MOF, termed Ru-NU-1000, shows excellent heterogeneous photocatalytic activity for an oxidative amine coupling reaction.

本文言語	英語
ページ（範囲）	30299-30305
ページ数	7
ジャーナル	ACS Omega
巻	5
号	46
DOI	https://doi.org/10.1021/acsomega.0c04823
出版ステータス	出版済み - 11月 24 2020

!!!All Science Journal Classification (ASJC) codes

化学 (全般)
化学工学（全般）

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10.1021/acsomega.0c04823

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引用スタイル

@article{64fc841d4db54e37b6d00a5d9bd009f3,

title = "Regioselective Functionalization of the Mesoporous Metal−Organic Framework, NU-1000, with Photo-Active Tris-(2,2′bipyridine)ruthenium(II)",

abstract = "Solvent-assisted ligand incorporation is an excellent method for the post-synthetic functionalization of Zr-based metal−organic frameworks (MOFs), as carboxylate-derivative functionalities readily coordinate to the Zr6 nodes by displacing node-based aqua and terminal hydroxo ligands. In this study, a photocatalytically active ruthenium complex RuII(bpy)2(dcbpy), that is, bis-(2,2′-bipyridine)-(4,4′-dicarboxy-2,2′-bipyridine)ruthenium, was installed in the mono-protonated (carboxylic acid) form within NU-1000 via SALI. Crystallographic information regarding the siting of the ruthenium complex within the MOF pores is obtained by difference envelope density analysis. The ruthenium-functionalized MOF, termed Ru-NU-1000, shows excellent heterogeneous photocatalytic activity for an oxidative amine coupling reaction.",

author = "Hisanori Nagatomi and Gallington, {Leighanne C.} and Subhadip Goswami and Jiaxin Duan and Chapman, {Karena W.} and Nobuhiro Yanai and Nobuo Kimizuka and Farha, {Omar K.} and Hupp, {Joseph T.}",

note = "Funding Information: We gratefully acknowledge support from the U.S. Dept. of Energy, Office of Science, Office of Basic Energy Sciences (grant no. DE-FG02-87ER13808) and Northwestern University. The X-ray work made use of the IMSERC at Northwestern University, which has received support from the Soft and Hybrid Nanotechnology Experimental (SHyNE) Resource (NSF NNCI-1542205), the State of Illinois, and the International Institute for Nanotechnology (IIN). The research for the DED analysis used resources of the Advanced Photon Source, a U.S. Department of Energy (DOE) Office of Science User Facility operated for the DOE Office of Science by Argonne National Laboratory under contract no. DE-AC02-06CH11357. H.N. was supported by the Leading Graduate School for Advanced Graduate Course on Molecular Systems for Devices of Kyushu University by MEXT (Ministry of Education, Culture, Sports, Science and Technology). Publisher Copyright: {\textcopyright} 2020 American Chemical Society. All rights reserved.",

year = "2020",

month = nov,

day = "24",

doi = "10.1021/acsomega.0c04823",

language = "English",

volume = "5",

pages = "30299--30305",

journal = "ACS Omega",

issn = "2470-1343",

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T1 - Regioselective Functionalization of the Mesoporous Metal−Organic Framework, NU-1000, with Photo-Active Tris-(2,2′bipyridine)ruthenium(II)

AU - Nagatomi, Hisanori

AU - Gallington, Leighanne C.

AU - Goswami, Subhadip

AU - Duan, Jiaxin

AU - Chapman, Karena W.

AU - Yanai, Nobuhiro

AU - Kimizuka, Nobuo

AU - Farha, Omar K.

AU - Hupp, Joseph T.

N1 - Funding Information: We gratefully acknowledge support from the U.S. Dept. of Energy, Office of Science, Office of Basic Energy Sciences (grant no. DE-FG02-87ER13808) and Northwestern University. The X-ray work made use of the IMSERC at Northwestern University, which has received support from the Soft and Hybrid Nanotechnology Experimental (SHyNE) Resource (NSF NNCI-1542205), the State of Illinois, and the International Institute for Nanotechnology (IIN). The research for the DED analysis used resources of the Advanced Photon Source, a U.S. Department of Energy (DOE) Office of Science User Facility operated for the DOE Office of Science by Argonne National Laboratory under contract no. DE-AC02-06CH11357. H.N. was supported by the Leading Graduate School for Advanced Graduate Course on Molecular Systems for Devices of Kyushu University by MEXT (Ministry of Education, Culture, Sports, Science and Technology). Publisher Copyright: © 2020 American Chemical Society. All rights reserved.

PY - 2020/11/24

Y1 - 2020/11/24

N2 - Solvent-assisted ligand incorporation is an excellent method for the post-synthetic functionalization of Zr-based metal−organic frameworks (MOFs), as carboxylate-derivative functionalities readily coordinate to the Zr6 nodes by displacing node-based aqua and terminal hydroxo ligands. In this study, a photocatalytically active ruthenium complex RuII(bpy)2(dcbpy), that is, bis-(2,2′-bipyridine)-(4,4′-dicarboxy-2,2′-bipyridine)ruthenium, was installed in the mono-protonated (carboxylic acid) form within NU-1000 via SALI. Crystallographic information regarding the siting of the ruthenium complex within the MOF pores is obtained by difference envelope density analysis. The ruthenium-functionalized MOF, termed Ru-NU-1000, shows excellent heterogeneous photocatalytic activity for an oxidative amine coupling reaction.

AB - Solvent-assisted ligand incorporation is an excellent method for the post-synthetic functionalization of Zr-based metal−organic frameworks (MOFs), as carboxylate-derivative functionalities readily coordinate to the Zr6 nodes by displacing node-based aqua and terminal hydroxo ligands. In this study, a photocatalytically active ruthenium complex RuII(bpy)2(dcbpy), that is, bis-(2,2′-bipyridine)-(4,4′-dicarboxy-2,2′-bipyridine)ruthenium, was installed in the mono-protonated (carboxylic acid) form within NU-1000 via SALI. Crystallographic information regarding the siting of the ruthenium complex within the MOF pores is obtained by difference envelope density analysis. The ruthenium-functionalized MOF, termed Ru-NU-1000, shows excellent heterogeneous photocatalytic activity for an oxidative amine coupling reaction.

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