Regioselective penta-addition of 1-alkenyl copper reagent to [60]fullerene. Synthesis of penta-alkenyl FCp ligand

Masaya Sawamura, Noriaki Nagahama, Motoki Toganoh, Eiichi Nakamura

研究成果: Contribution to journalArticle

16 引用 (Scopus)

抜粋

We have found the conditions to achieve penta-addition of an alkenyl group to [60]fullerene in good yield with the aid of an RCu-type reagent prepared from the corresponding alkenyllithium reagent. The addition took place regioselectively at the five double bonds surrounding a pentagon in the fullerene and with retention of the stereochemistry of the alkenylcopper reagent. The reaction thus produced a cyclopentadiene embedded in the fullerene core that bears five 1-alkenyl groups (1c-e).

元の言語英語
ページ(範囲)31-35
ページ数5
ジャーナルJournal of Organometallic Chemistry
652
発行部数1-2
DOI
出版物ステータス出版済み - 6 1 2002
外部発表Yes

All Science Journal Classification (ASJC) codes

  • Biochemistry
  • Physical and Theoretical Chemistry
  • Organic Chemistry
  • Inorganic Chemistry
  • Materials Chemistry

フィンガープリント Regioselective penta-addition of 1-alkenyl copper reagent to [60]fullerene. Synthesis of penta-alkenyl FCp ligand' の研究トピックを掘り下げます。これらはともに一意のフィンガープリントを構成します。

  • これを引用