Regulation of a cerium(iv)-driven O2 evolution reaction using composites of liposome and lipophilic ruthenium complexes

Tomomi Koshiyama, Nao Kanda, Koki Iwata, Masayuki Honjo, Sana Asada, Tatsuru Hatae, Yasuhiro Tsuji, Masaki Yoshida, Masaya Okamura, Reiko Kuga, Shigeyuki Masaoka, Masaaki Ohba

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抜粋

A composite containing a liposome and a lipophilic ruthenium complex was synthesized to regulate an O2 evolution reaction using cerium(iv) ammonium nitrate as an oxidizing reagent. We found that the surrounding environment of the reaction centre is an important factor for controlling the O2 evolution catalytic reaction. We successfully regulated the reaction activity using the linker length of the lipophilic ligand and using the head groups of the phospholipid component.

元の言語英語
ページ(範囲)15126-15129
ページ数4
ジャーナルDalton Transactions
44
発行部数34
DOI
出版物ステータス出版済み - 4 29 2015

All Science Journal Classification (ASJC) codes

  • Inorganic Chemistry

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    Koshiyama, T., Kanda, N., Iwata, K., Honjo, M., Asada, S., Hatae, T., Tsuji, Y., Yoshida, M., Okamura, M., Kuga, R., Masaoka, S., & Ohba, M. (2015). Regulation of a cerium(iv)-driven O2 evolution reaction using composites of liposome and lipophilic ruthenium complexes. Dalton Transactions, 44(34), 15126-15129. https://doi.org/10.1039/c5dt00793c