Remarkably improved hydrogen storage properties of LiNH2-LiH composite via the addition of CeF4

Huai Jun Lin, Hai Wen Li, Hiroki Murakami, Etsuo Akiba

研究成果: Contribution to journalArticle査読

14 被引用数 (Scopus)

抄録

Amide-hydride composite materials, such as LiNH2–LiH and Mg(NH2)2–2LiHcomposites, are promising candidates for hydrogen storage due to the high hydrogen storage capacity and moderate hydrogen storage enthalpies and entropies. However, the hydrogen absorption/desorption kinetics of the amide-based system is too sluggish, and emission of ammonia (NH3) during dehydrogenation also fatally deteriorates the hydrogen storage cyclic ability. In this study, we report that CeF4 shows a remarkable catalytic effect in improving hydrogen storage kinetic and cyclic properties, reducing dehydrogenation temperature, and suppressing emission of NH3 of LiNH2-LiH composite. Mechanism study reveals that the catalysis should be due to the in situ formed F-containing CeFx species during ball milling process.

本文言語英語
ページ(範囲)1017-1022
ページ数6
ジャーナルJournal of Alloys and Compounds
735
DOI
出版ステータス出版済み - 2 25 2018

All Science Journal Classification (ASJC) codes

  • 材料力学
  • 機械工学
  • 金属および合金
  • 材料化学

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