Reversible formation of self-assembly gels containing giant vesicles in trifluoromethylbenzene using oxymethylenehelicene oligomers with terminal C16 alkyl groups

Tsukasa Sawato, Mieko Arisawa, Masahiko Yamaguchi

研究成果: ジャーナルへの寄稿学術誌査読

3 被引用数 (Scopus)

抄録

A 1:1 mixture of pseudoenantiomeric oxymethylenehelicene (P)-pentamer and (M)-hexamer with terminal C16 alkyl groups in trifluoromethylbenzene formed hetero-double-helices and their self-assembly gels. The gels contained giant vesicles with concentric structures possessing an average diameter in the range of 2030 ¯m, and the introduction of the C16 alkyl groups on the oligomers was essential for their formation. Heating and cooling reversibly decomposed and formed the gel containing giant vesicles in the nonpolar organic solvent, thereby showing thermal hysteresis.

本文言語英語
ページ(範囲)1497-1503
ページ数7
ジャーナルBulletin of the Chemical Society of Japan
93
12
DOI
出版ステータス出版済み - 12月 2020
外部発表はい

!!!All Science Journal Classification (ASJC) codes

  • 化学 (全般)

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