Rh-catalyzed direct enantioselective alkynylation of α-ketiminoesters

Kazuhiro Morisaki, Masanao Sawa, Jun Ya Nomaguchi, Hiroyuki Morimoto, Yosuke Takeuchi, Kazushi Mashima, Takashi Ohshima

研究成果: ジャーナルへの寄稿記事

46 引用 (Scopus)

抜粋

A green way to amino acids: α-Tetrasubstituted α-amino acid derivatives are formed in high yield and enantioselectivity by using a Rh-catalyzed enantioselective alkynylation of α-ketiminoesters. This reaction, which involves a proton transfer and can be conducted at room temperature, has high substrate scope (see scheme; Cbz=benzyloxycarbonyl, Fmoc=9-fluorenylmethyloxycarbonyl).

元の言語英語
ページ(範囲)8417-8420
ページ数4
ジャーナルChemistry - A European Journal
19
発行部数26
DOI
出版物ステータス出版済み - 6 24 2013

    フィンガープリント

All Science Journal Classification (ASJC) codes

  • Catalysis
  • Organic Chemistry

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