Rhenium-catalyzed formation of bicyclo[3.3.1]nonene frameworks by a reaction of cyclic β-keto esters with terminal alkynes

Yoichiro Kuninobu, Junya Morita, Mitsumi Nishi, Atsushi Kawata, Kazuhiko Takai

研究成果: Contribution to journalArticle査読

26 被引用数 (Scopus)

抄録

Treatment of cyclic βKeto esters with terminal alkynes in the presence of a catalytic amount of a rhenium complex, [ReBr(CO)3(thf)] 2, gave bicyclo[3.3.1]nonene derivatives. The reaction conditions and yields of the bicyclo[3.3.1]nonenes were improved by the sequential use of tetrabutylammonium fluoride (TBAF) after the rhenium-catalyzed reactions.

本文言語英語
ページ(範囲)2535-2537
ページ数3
ジャーナルOrganic Letters
11
12
DOI
出版ステータス出版済み - 6 18 2009
外部発表はい

All Science Journal Classification (ASJC) codes

  • Biochemistry
  • Physical and Theoretical Chemistry
  • Organic Chemistry

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