Rhenium-catalyzed insertion of terminal alkenes into a C(sp2)-H bond and successive transfer hydrogenation

Yoichiro Kuninobu, Takahiro Nakahara, Peng Yu, Kazuhiko Takai

研究成果: ジャーナルへの寄稿記事

7 引用 (Scopus)

抄録

Treatment of aromatic aldimines with terminal alkenes in the presence of a rhenium catalyst, [HRe(CO)4]n, gives 2-alkenylbenzylamines in good to excellent yields. This reaction proceeds via the insertion of the alkene into a C-H bond at the ortho-position of the imino group of the aromatic aldimine followed by sequential β-hydride elimination from the formed alkyl rhenium intermediate and then by hydrogenation of the imino group of the aldimine.

元の言語英語
ページ(範囲)348-351
ページ数4
ジャーナルJournal of Organometallic Chemistry
696
発行部数1
DOI
出版物ステータス出版済み - 1 1 2011

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Rhenium
Hydrogenation
rhenium
Alkenes
alkenes
Olefins
hydrogenation
insertion
Carbon Monoxide
Hydrides
hydrides
elimination
catalysts
Catalysts

All Science Journal Classification (ASJC) codes

  • Biochemistry
  • Physical and Theoretical Chemistry
  • Organic Chemistry
  • Inorganic Chemistry
  • Materials Chemistry

これを引用

Rhenium-catalyzed insertion of terminal alkenes into a C(sp2)-H bond and successive transfer hydrogenation. / Kuninobu, Yoichiro; Nakahara, Takahiro; Yu, Peng; Takai, Kazuhiko.

:: Journal of Organometallic Chemistry, 巻 696, 番号 1, 01.01.2011, p. 348-351.

研究成果: ジャーナルへの寄稿記事

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AB - Treatment of aromatic aldimines with terminal alkenes in the presence of a rhenium catalyst, [HRe(CO)4]n, gives 2-alkenylbenzylamines in good to excellent yields. This reaction proceeds via the insertion of the alkene into a C-H bond at the ortho-position of the imino group of the aromatic aldimine followed by sequential β-hydride elimination from the formed alkyl rhenium intermediate and then by hydrogenation of the imino group of the aldimine.

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