Rhenium-templated regioselective polyhydrogenation reaction of [60]fullerene

Motoki Toganoh; Yutaka Matsuo; Eiichi Nakamura

doi:10.1002/anie.200351722

Rhenium-templated regioselective polyhydrogenation reaction of [60]fullerene

Motoki Toganoh, Yutaka Matsuo, Eiichi Nakamura

研究成果: Contribution to journal › Article › 査読

33 被引用数 (Scopus)

抄録

Functionalizing fullerenes: The first regioselective polyhydrogenation of [60]fullerene has been achieved. Upon treatment of [60]fullerene or its derivative with 9,10-dihydroanthracene in the presence of [Re ₂(CO)₁₀], transfer hydrometallation reaction takes place to give a polyhydrogenation product (see scheme). The reaction provided a pathway to a variety of metal η⁵ complexes of hydrofullerenes.

本文言語	英語
ページ（範囲）	3530-3532
ページ数	3
ジャーナル	Angewandte Chemie - International Edition
巻	42
号	30
DOI	https://doi.org/10.1002/anie.200351722
出版ステータス	出版済み - 8 4 2003
外部発表	はい

All Science Journal Classification (ASJC) codes

触媒
化学 (全般)

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10.1002/anie.200351722

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abstract = "Functionalizing fullerenes: The first regioselective polyhydrogenation of [60]fullerene has been achieved. Upon treatment of [60]fullerene or its derivative with 9,10-dihydroanthracene in the presence of [Re 2(CO)10], transfer hydrometallation reaction takes place to give a polyhydrogenation product (see scheme). The reaction provided a pathway to a variety of metal η5 complexes of hydrofullerenes.",

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Rhenium-templated regioselective polyhydrogenation reaction of [60]fullerene

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