Rhodium-catalyzed synthesis of silafluorene derivatives via cleavage of silicon-hydrogen and carbon-hydrogen bonds

Tomonari Ureshino, Takuya Yoshida, Yoichiro Kuninobu, Kazuhiko Takai

研究成果: ジャーナルへの寄稿記事

152 引用 (Scopus)

抄録

The rhodium-catalyzed synthesis of silafluorenes from biphenylhydrosilanes is described. This highly efficient reaction proceeds via both Si-H and C-H bond activation, producing only H2 as a side product. Using this method, a ladder-type bis-silicon-bridged p-terphenyl could also be synthesized.

元の言語英語
ページ(範囲)14324-14326
ページ数3
ジャーナルJournal of the American Chemical Society
132
発行部数41
DOI
出版物ステータス出版済み - 10 20 2010
外部発表Yes

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Rhodium
Ladders
Silicon
Hydrogen
Hydrogen bonds
Carbon
Chemical activation
Derivatives

All Science Journal Classification (ASJC) codes

  • Catalysis
  • Chemistry(all)
  • Biochemistry
  • Colloid and Surface Chemistry

これを引用

Rhodium-catalyzed synthesis of silafluorene derivatives via cleavage of silicon-hydrogen and carbon-hydrogen bonds. / Ureshino, Tomonari; Yoshida, Takuya; Kuninobu, Yoichiro; Takai, Kazuhiko.

:: Journal of the American Chemical Society, 巻 132, 番号 41, 20.10.2010, p. 14324-14326.

研究成果: ジャーナルへの寄稿記事

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