Rhodium(I)/Chiral Diene-Catalyzed Enantioselective Addition of Boronic Acids to N-Unsubstituted Isatin-Derived Ketimines

Ryohei Yonesaki, Ibuki Kusagawa, Hiroyuki Morimoto, Tamio Hayashi, Takashi Ohshima

研究成果: ジャーナルへの寄稿学術誌査読

8 被引用数 (Scopus)

抄録

Enantioselective addition of boronic acids to N-unsubstituted isatin-derived ketimines was realized using rhodium(I)/chiral diene catalysts. The reactions can be performed in the presence of catalytic amounts of a base to give adducts in high yield with high enantioselectivity. Preliminary mechanistic information including a computational model to explain the observed enantioselectivity is also provided.

本文言語英語
ページ(範囲)499-502
ページ数4
ジャーナルChemistry - An Asian Journal
15
4
DOI
出版ステータス印刷中 - 1月 1 2020

!!!All Science Journal Classification (ASJC) codes

  • 生化学
  • 有機化学

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