Role of the particle size of Fe nanoparticles in the capacity of FeF3 batteries

Tsuyoshi Takami, Keitaro Matsui, Hiroshi Senoh, Masahiro Shikano, Hikari Sakaebe, Toshiharu Fukunaga

研究成果: Contribution to journalArticle査読

4 被引用数 (Scopus)

抄録

Fluoride cathode materials that undergo conversion reactions such as FeF3 have attracted increasing interest owing to their high energy density. However, the ability of FeF3 to maintain a high capacity over repeated cycles and the decisive factor dominating conversion reactions have yet to be elucidated. By optimizing the choice of lithium salts and electrolyte solutions, we are able to achieve good capacity retention for an FeF3-based cathode, that is, 4.5-fold enhancement compared with a model electrode (372 mAh/g after 30 cycles). The relationship between the capacity and the particle size of the Fe nanoparticles after discharge is well explained by the order parameter description. These findings provide exciting guidelines for achieving higher capacities for FeF3 batteries.

本文言語英語
論文番号045301
ジャーナルAIP Advances
9
4
DOI
出版ステータス出版済み - 4 1 2019
外部発表はい

All Science Journal Classification (ASJC) codes

  • 物理学および天文学(全般)

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