Rotational Dynamics of a Probe in Rubbery Polymers Characterized by Time-Resolved Fluorescence Anisotropy Measurement

Hung K. Nguyen, Asuka Konomi, Shin Sugimoto, Manabu Inutsuka, Daisuke Kawaguchi, Keiji Tanaka

研究成果: ジャーナルへの寄稿記事

2 引用 (Scopus)

抄録

The rotational relaxation time (τrot) of a fluorescent molecule, coumarin 153 (C153), dispersed in different rubbery polymers is characterized by time-resolved fluorescence anisotropy measurement, and an attempt is made to quantitatively combine it with the segmental relaxation time (τseg) of the corresponding matrix polymer obtained by dielectric relaxation spectroscopy. This study here demonstrates that τseg extrapolated to higher temperatures using the Vogel–Fulcher–Tammann law can be superimposed on τrot, resulting in a single curve. This behavior is common for polymers with different glass transition temperatures such as polyisoprene and acrylonitrile/butadiene copolymer, implying that the rotational dynamics of C153 is a useful tool for the characterization of polymer dynamics.

元の言語英語
記事番号1700329
ジャーナルMacromolecular Chemistry and Physics
219
発行部数3
DOI
出版物ステータス出版済み - 2 1 2018

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Relaxation time
Polymers
Anisotropy
Fluorescence
fluorescence
anisotropy
probes
relaxation time
polymers
Acrylonitrile
Polyisoprenes
Dielectric relaxation
Butadiene
Polymer matrix
polyisoprenes
acrylonitriles
Copolymers
butadiene
Spectroscopy
glass transition temperature

All Science Journal Classification (ASJC) codes

  • Condensed Matter Physics
  • Physical and Theoretical Chemistry
  • Polymers and Plastics
  • Organic Chemistry
  • Materials Chemistry

これを引用

Rotational Dynamics of a Probe in Rubbery Polymers Characterized by Time-Resolved Fluorescence Anisotropy Measurement. / Nguyen, Hung K.; Konomi, Asuka; Sugimoto, Shin; Inutsuka, Manabu; Kawaguchi, Daisuke; Tanaka, Keiji.

:: Macromolecular Chemistry and Physics, 巻 219, 番号 3, 1700329, 01.02.2018.

研究成果: ジャーナルへの寄稿記事

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