抄録
Reactions of the coordinatively unsaturated complexes [(η6-C6Me6)Ru{η-iPrNC(Me) = NiPr}]+X- with Me3SiCHN2 resulted in the formation of the amidinato-carbene complexes [(η6-C6Me6)Ru{=CHNiPrC(Me) = NiPr}(SiMe3)]+ X-, in which a trimethylsilyl group is bonded to the ruthenium atom. Migration of the silyl group to the carbene ligand occurred on reaction with CO, whereas the reverse reaction was promoted by photochemical dissociation of CO.
本文言語 | 英語 |
---|---|
ページ(範囲) | 4996-4998 |
ページ数 | 3 |
ジャーナル | Organometallics |
巻 | 20 |
号 | 24 |
DOI | |
出版ステータス | 出版済み - 11月 26 2001 |
!!!All Science Journal Classification (ASJC) codes
- 物理化学および理論化学
- 有機化学
- 無機化学