Ruthenium-catalyzed selective and efficient oxygenation of hydrocarbons with water as an oxygen source

Yuichirou Hirai, Takahiko Kojima, Yasuhisa Mizutani, Yoshihito Shiota, Kazunari Yoshizawa, Shunichi Fukuzumi

研究成果: Contribution to journalArticle査読

111 被引用数 (Scopus)

抄録

(Chemical Equation Presented) Water is not only the solvent but also the sole oxygen source in the smooth and efficient oxidation of organic compounds catalyzed by a RuII-pyridylamine-aqua complex with CeIV as the oxidant. An intermediate-spin RuIV-oxo complex is formed as the reactive species (see scheme; Sub = substrate). This catalytic system is durable and able to gain high turnover numbers for various substrates.

本文言語英語
ページ(範囲)5772-5776
ページ数5
ジャーナルAngewandte Chemie - International Edition
47
31
DOI
出版ステータス出版済み - 7 21 2008

All Science Journal Classification (ASJC) codes

  • Catalysis
  • Chemistry(all)

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