Saccharide Recognition by Amphiphilic Diboronic Acids at the Air-Water Interface and the Relationship between Selectivity and Stoichiometry

Rainer Ludwig, Yutaka Shiomi, Seiji Shinkai

研究成果: ジャーナルへの寄稿記事

22 引用 (Scopus)

抄録

Amphiphilic diphenylmethane-3,3′-diboronic acids form stable monolayers which selectively bind monosaccharides. The selectivity order expressed as a difference in the collapse pressure between the uncomplexed and complexed boronic acid monolayer is governed by the formation of complexes consisting of two diboronic acid molecules bridged by one sugar molecule. The selectivity can be changed to correlate with the order of the association constants of the 1:1 complexes in homogeneous solution by adding polycations to the subphase or by diluting the monolayer with amphiphilic quaternized ammonium ions.

元の言語英語
ページ(範囲)3195-3200
ページ数6
ジャーナルLangmuir
10
発行部数9
DOI
出版物ステータス出版済み - 9 1 1994
外部発表Yes

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carbohydrates
Stoichiometry
stoichiometry
Monolayers
selectivity
acids
Acids
Water
air
Air
Boronic Acids
water
monosaccharides
Molecules
Monosaccharides
sugars
Ammonium Compounds
Sugars
molecules
Association reactions

All Science Journal Classification (ASJC) codes

  • Materials Science(all)
  • Condensed Matter Physics
  • Surfaces and Interfaces
  • Spectroscopy
  • Electrochemistry

これを引用

Saccharide Recognition by Amphiphilic Diboronic Acids at the Air-Water Interface and the Relationship between Selectivity and Stoichiometry. / Ludwig, Rainer; Shiomi, Yutaka; Shinkai, Seiji.

:: Langmuir, 巻 10, 番号 9, 01.09.1994, p. 3195-3200.

研究成果: ジャーナルへの寄稿記事

Ludwig, Rainer ; Shiomi, Yutaka ; Shinkai, Seiji. / Saccharide Recognition by Amphiphilic Diboronic Acids at the Air-Water Interface and the Relationship between Selectivity and Stoichiometry. :: Langmuir. 1994 ; 巻 10, 番号 9. pp. 3195-3200.
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