Selective separation of water, methanol, and ethanol by a porous coordination polymer built with a flexible tetrahedral ligand

Akihito Shigematsu, Teppei Yamada, Hiroshi Kitagawa

研究成果: ジャーナルへの寄稿学術誌査読

137 被引用数 (Scopus)

抄録

A novel porous coordination polymer, CuII(mtpm)Cl2 [mtpm = tetrakis(m-pyridyloxy methylene)methane], has been synthesized, and its crystal structure has been determined. Its adsorption isotherms for water, methanol, and ethanol are totally different from each other. It adsorbs water at low humidity and shows gate-open behavior for methanol, but it does not adsorb ethanol. This compound has the capacity to separate both methanol and water from bioethanol, which is a mixture of water, methanol, and ethanol.

本文言語英語
ページ(範囲)13145-13147
ページ数3
ジャーナルJournal of the American Chemical Society
134
32
DOI
出版ステータス出版済み - 8月 15 2012
外部発表はい

!!!All Science Journal Classification (ASJC) codes

  • 触媒
  • 化学 (全般)
  • 生化学
  • コロイド化学および表面化学

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