Self-Assembly of a Double Hydrophilic Block Glycopolymer and the Investigation of Its Mechanism

Takahiro Oh, Masanori Nagao, Yu Hoshino, Yoshiko Miura

研究成果: Contribution to journalArticle

8 引用 (Scopus)

抜粋

We report the self-assembly of a double hydrophilic block glycopolymer (DHBG) via hydrogen bonding and coordinate bonding. This DHBG, composed of poly(ethylene)glycol (PEG) and glycopolymer, self-assembled into a well-defined structure. The DHBG was prepared through the controlled radical polymerization of trimethylsilyl-protected propargyl methacrylate using a PEG-based reversible addition-fragmentation chain transfer reagent, followed by sugar conjugation using click chemistry. The DHBG self-assembly capability was investigated by transmission electron microscopy and dynamic light scattering. Interestingly, the DHBG self-assembled into a spherical structure in aqueous solution. Hydrogen bonding and coordinate bonding with Ca2+ were identified as the driving forces for self-assembly.

元の言語英語
ページ(範囲)8591-8598
ページ数8
ジャーナルLangmuir
34
発行部数29
DOI
出版物ステータス出版済み - 7 24 2018

All Science Journal Classification (ASJC) codes

  • Materials Science(all)
  • Condensed Matter Physics
  • Surfaces and Interfaces
  • Spectroscopy
  • Electrochemistry

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