Self-assembly of oligo(ethylene oxide)-linked diammonium ions with polyoxometalates into ordered polyhedron nanocrystals in aqueous media

Keita Ishiba, Daisuke Kichise, Hiroaki Iguchi, Masa Aki Morikawa, Nobuo Kimizuka

    研究成果: ジャーナルへの寄稿学術誌査読

    抄録

    Self-assembly of Keggin-type polyoxometalates (POMs) with diammonium ions containing oligo(ethylene oxide) units form parallelepiped or octahedral nanocrystals. These structures are tunable depending on the chemical structure of the ammonium ions and preparative conditions. The ether linkages in these ammonium ions exert conformational flexibility, which is essential to achieve long-range regular molecular alignments in the nanocrystals.

    本文言語英語
    ページ(範囲)430-433
    ページ数4
    ジャーナルChemistry Letters
    46
    4
    DOI
    出版ステータス出版済み - 2017

    !!!All Science Journal Classification (ASJC) codes

    • 化学 (全般)

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