Short synthesis of (+)-cylindricine C by using a catalytic asymmetric Michael reaction with a two-center organocatalyst

Tomoyuki Shibuguchi; Hisashi Mihara; Akiyoshi Kuramochi; Shun Sakuraba; Takashi Ohshima; Masakatsu Shibasaki

doi:10.1002/anie.200601722

Short synthesis of (+)-cylindricine C by using a catalytic asymmetric Michael reaction with a two-center organocatalyst

Tomoyuki Shibuguchi, Hisashi Mihara, Akiyoshi Kuramochi, Shun Sakuraba, Takashi Ohshima, Masakatsu Shibasaki

研究成果: Contribution to journal › Article › 査読

77 被引用数 (Scopus)

抄録

(Chemical Equation Presented) Two for the price of one: The total synthesis of (+)-cylindricine C has been achieved in six steps using a catalytic asymmetric Michael reaction and tandem cyclization. A newly designed two-center organocatalyst gives good selectivity in this Michael reaction. TaDiAS = tartrate-derived diammonium salt.

本文言語	英語
ページ（範囲）	4635-4637
ページ数	3
ジャーナル	Angewandte Chemie - International Edition
巻	45
号	28
DOI	https://doi.org/10.1002/anie.200601722
出版ステータス	出版済み - 7 10 2006
外部発表	はい

All Science Journal Classification (ASJC) codes

Catalysis
Chemistry(all)

文献へのアクセス

10.1002/anie.200601722

他のファイルとリンク

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引用スタイル

Short synthesis of (+)-cylindricine C by using a catalytic asymmetric Michael reaction with a two-center organocatalyst. / Shibuguchi, Tomoyuki; Mihara, Hisashi; Kuramochi, Akiyoshi; Sakuraba, Shun; Ohshima, Takashi; Shibasaki, Masakatsu.

In: Angewandte Chemie - International Edition, Vol. 45, No. 28, 10.07.2006, p. 4635-4637.

研究成果: Contribution to journal › Article › 査読

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